doi:10.16597/j.cnki.issn.1002-154x.2022.12.004
可降解丙烯酸酯类高分子材料的合成研究
沈杰
(湖北省化学工业研究设计院,湖北 武汉 430073)
Synthesis of Acrylate Polymer Materials with Degradation
Shen Jie
(Hubei Chemical Industry Research and Design Institute, Hubei Wuhan 430073)
摘要:
高分子材料在带给人们便利的同时,也带来了极大的环境危机,如何有效提高高分子材料的降解性能至关重要。作者以庚醛、香茅醛、肉桂醛、紫苏醛获取的生物质平台化合物作为基本原料,运用一锅法烯丙基化/内酯化反应,成功获得了4种不同的α-亚甲基-γ-丁内酯(MBL)生物质单体,各方面均能够满足持续降解的丙烯酸酯类高分子材料的要求。
关键词：可降解；丙烯酸酯类；高分子材料；合成；
Abstract：
Synthetic polymer materials brings convenience, and brings great environmental crisis. How to effectively improve the degradation performance of polymer materials is very important. In this study, using the biomass obtained from heptanaldehyde, citronellal, cinnamaldehyde and perilla aldehyde as basic raw materials, four different MBL biomass monomers were successfully obtained by one pot zinc mediated allylation / lactonization reaction, which can meet the requirements of continuously degraded acrylate polymer materials in all aspects.
Keywords：degradation; acrylate; polymer materials; synthesis;